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Dominant species
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Cassiterite
Cassiterite
Chemical
Formula
SnO2
Species
Oxides & Hydroxides
Crystal
System
Tetragonal
Mohs
Scale
6-7
Specific
Gravity
6.98-7.1
Color
Black, brownish black, reddish brown, red, yellow, gray, white; rarely colorless
Streak
White to brownish
Luster
Adamantine, Greasy, Sub-Metallic
Refractive
Index
n = 1.990 - 2.010 n = 2.093 - 2.100
Diaphaneity
Transparent, Translucent, Opaque
Cleavage
Imperfect/Fair imperfect, indistinct.
Fracture
Irregular/Uneven, Sub-Conchoidal
Crystal Habit:Pyramidic, prismatic, radially fibrous botryoidal crusts and concretionary masses; coarse to fine granular, massive
Geological Setting:In medium- to high-temperature hydrothermal veins and greisens, alluvial placers.
Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite has been the chief tin ore throughout ancient history and remains the most important source of tin today.

Occurrence

Most sources of cassiterite today are found in alluvial or placer deposits containing the resistant weathered grains. The best sources of primary cassiterite are found in the tin mines of Bolivia, where it is found in hydrothermal veins. Rwanda has a nascent cassiterite mining industry. Fighting over cassiterite deposits (particularly in Walikale) is a major cause of the conflict waged in eastern parts of the Democratic Republic of the Congo.

Cassiterite is a widespread minor constituent of igneous rocks. The Bolivia veins and the old exhausted workings of Cornwall, England, are concentrated in high temperature quartz veins and pegmatites associated with granitic intrusives. The veins commonly contain tourmaline, topaz, fluorite, apatite, wolframite, molybdenite, and arsenopyrite. The mineral occurs extensively in Cornwall as surface deposits on Bodmin Moor for example, where there are extensive traces of an hydraulic mining method known as streaming. The current major tin production comes from placer or alluvial deposits in Malaysia, Thailand, Indonesia, Maakhir region of Somalia, and Russia. Hydraulic mining methods are used to concentrate the fine particles of ore owing to its high specific gravity of about 7.0 G.

Crystallography

Crystal twinning is common in cassiterite and most aggregate specimens show crystal twins. The typical twin is bent at a near-60-degree angle, forming an "elbow twin". Botryoidal or reniform cassiterite is called wood tin.

Cassiterite is also used as a gemstone and collector specimens when quality crystals are found.

Etymology

The name derives from the Greek kassiteros for "tin"—or from the Phoenician word Cassiterid referring to the islands of Ireland and Britain, the ancient sources of tin—or, as Roman Ghirshman (1954)[citation needed] suggests, from the region of the Kassites, an ancient people in west and central Iran.