9 Photos
Pyrolusite
Chemical Formula	MnO2
Species	Oxides & Hydroxides
Crystal System	Tetragonal
Mohs Scale	2-6
Specific Gravity	4.4-5.06
Color	Darkish, black to lighter grey, somethimes bluish
Streak	Black to bluish-black
Luster	Metallic, Dull, Earthy
Refractive Index	Opaque
Diaphaneity	Opaque
Cleavage	PerfectPerfect on .
Fracture	Irregular/Uneven
Crystal Habit：Granular to massive: botryoidal and dendritic. Crystals rare
Geological Setting：A common Mn mineral, although difficult to distinguish from similar Mn minerals, pyrolusite forms under oxidizing conditions and high pH. Mainly a mineral of lacustrine, shallow marine, and bog deposits, it is also found in the oxidized zones of manganiferous ore deposits and as deposits formed by circulating meteoric water. Both colloidal processes and bacterial action are important in its formation.

Pyrolusite is a mineral consisting essentially of manganese dioxide (MnO₂) and is important as an ore of manganese. It is a black, amorphous appearing mineral, often with a granular, fibrous or columnar structure, sometimes forming reniform crusts. It has a metallic luster, a black or bluish-black streak, and readily soils the fingers. The specific gravity is about 4.8. Its name is from the Greek for fire and to wash, in reference to its use as a way to remove tints from glass.

Occurrence

Pyrolusite and romanechite are among the most common manganese minerals. Pyrolusite occurs associated with manganite, hollandite, hausmannite, braunite, chalcophanite, goethite and hematite under oxidizing conditions in hydrothermal deposits. It also occurs in bogs and often results from alteration of manganite.

Use

The metal is obtained by reduction of the oxide with sodium, magnesium, aluminium, or by electrolysis. Pyrolusite is extensively used for the manufacture of spiegeleisen and ferromanganese and of various alloys such as manganese-bronze. As an oxidizing agent it is used in the preparation of chlorine; indeed, chlorine gas itself was first described by Karl Scheele in 1774 from the reaction products of pyrolusite and hydrochloric acid. Natural pyrolusite has been used in batteries, but high-quality batteries requires synthetic products. Pyrolusite is also used to prepare disinfectants (permanganates) and for decolorizing glass. When mixed with molten glass it oxidizes the ferrous iron to ferric iron, and so discharges the green and brown tints (making it classically useful to glassmakers as a decolorizer). As a coloring material, it is used in calico printing and dyeing; for imparting violet, amber, and black colors to glass, pottery, and bricks; and in the manufacture of green and violet paints.

Variations in crystal habit