Structure is analogous to that of analcime with Be and Si in tetrahedral co-ordination forming a three-dimensional framework. Its space group is I213 (Previously reported as I4132). Unit cell parameters are a = 12.879 or 12.897, and Z = 8.
It occurs within phlogopite veins in the light-coloured band of green and white banded metamorphosed Devonian limestone which has been intruded by beryllium-bearing granite. Associated mineral include fluorite, liberite, chrysoberyl, taaffeite and nigerite.
Hsianghualite has been found only at the type locality, the Xianghualing Mine in Linwu County, Hunan Province, China.