It was first described in 1907 by George D. Louderback, who named it benitoite for its occurrence near the headwaters of the San Benito River in San Benito County, California.
Benitoite occurs in a number of sites, but gemstone quality material has only been found in California.[citation needed] It is California's official state gem.
Benitoite typically occurs with an unusual set of minerals, along with minerals that make up its host rock. Frequently associated minerals include: natrolite, neptunite, joaquinite, serpentine and albite.
Benitoite is a rare mineral found in very few locations including San Benito County, California, Japan and Arkansas. In the San Benito occurrence, it is found in natrolite veins within glaucophane schist within a serpentinite body. In Japan, the mineral occurs in a magnesio-riebeckite-quartz-phlogopite-albite dike cutting a serpentinite body.
In 1985 benitoite was named as the official state gem of California.