Alabandite was first described in 1784 by Franz-Joseph Müller von Reichenstein. The mineral name is derived from its supposed discovery locality at Alabanda (A?din) in Turkey.
Alabandite forms in epithermal polymetallic sulfide veins and low-temperature manganese deposits. It occurs with acanthite, calcite, chalcopyrite, galena, pyrite, quartz, rhodochrosite, rhodonite, sphalerite and native tellurium. Sometimes it was found in meteorites.
Localities are several areas in Antarctica, Argentina, Armenia, Australia, Bolivia, Brazil, Bulgaria, Canada, China, Czech Republic, Finland, France, Germany, Ghana, Greece, Greenland, India, Italy, Japan, Kyrgyzstan, Mexico, New Zealand, Norway, Peru, Poland, Romania, Russia, Slovakia, South Africa, South Korea, Sweden, Switzerland, Taiwan, Tanzania, the United Kingdom, the USA, Uzbekistan and Yemen. Altogether at present time approximately 220 discovery sites are registered.
Alabandite crystallizes in the cubic crystal system in the space group Fm3m with the lattice parameter a = 5.22 ? and four formula units per unit cell.